U.S. Geological Survey Geochemical Reference Materials and Certificates
U.S. Geological Survey
Certificate of Analysis
Sample for this reference material was collected from the Mahogany zone of the Green River Formation. It is a petroleum and carbonate-rich shale. At the time of preparation, shale oil tests yield 51 to 57 gallons per ton.
Element concentrations were determined by cooperating laboratories using a variety of analytical methods. Certificate values are based primarily on international data compilations (Abbey, 1983, Gladney and Roelandts, 1988, Govindaraju, 1994). Initial USGS studies (Flanagan, 1976) provide limited background information on this reference material.
Recommended Values | Certificate Information | Bibliography | Glossary | Notes | Order and Pricing Information
| Oxide | Wt % | ± | Oxide | Wt % | ± | |
|---|---|---|---|---|---|---|
| SiO2 | 28.2 | 0.21 | CaO | 8.38 | 0.17 | |
| Al2O3 | 6.52 | 0.21 | MgO | 4.44 | 0.20 | |
| K2O | 1.66 | 0.10 | P2O5 | 0.328 | 0.066 | |
| Na2O | 2.99 | 0.13 | TiO2 | 0.253 | 0.025 | |
| Fe2O3 T | 3.03 | 0.14 | Stot | 1.53 | 0.11 |
| Element | µg/g | ± | Element | µg/g | ± | Element | µg/g | ± | ||
|---|---|---|---|---|---|---|---|---|---|---|
| As | 67 | 5 | Eu | 0.56 | 0.09 | Sb | 3.4 | 0.5 | ||
| B | 54 | 3 | F | 1960 | 240 | Sc | 4.6 | 0.7 | ||
| Ba | 290 | 40 | Hf | 1.4 | 0.14 | Sm | 2.7 | 0.3 | ||
| Ce | 36 | 4 | La | 20 | 1.8 | Sr | 420 | 30 | ||
| Co | 12 | 1.5 | Li | 147 | 26 | Th | 4.8 | 0.21 | ||
| Cr | 30 | 3 | Mn | 267 | 34 | U | 5.4 | 0.4 | ||
| Cs | 5.2 | 0.3 | Mo | 35 | 0.9 | V | 130 | 6 | ||
| Cu | 66 | 9 | Nd | 16 | 1.7 | W | 2.6 | 0.06 | ||
| Er | 1.1 | 0.14 | Pb | 38 | 4 | Zn | 74 | 9 |
| Oxide | Wt % | Oxide | Wt % | |
|---|---|---|---|---|
| Fe2O3 | 4.19 | FeO | 0.90 | |
| Ctot | 3.16 | |||
| Element | µg/g | Element | µg/g | Element | µg/g | ||
|---|---|---|---|---|---|---|---|
| Cd | 0.9 | Ho | 0.4 | Sn | 1.9 | ||
| Cl | 32 | Li | 147 | Tm | 0.17 | ||
| Dy | 1.9 | Nb | 5.2 | Y | 13 | ||
| Ga | 12 | Ni | 29 | Yb | 0.94 | ||
| Gd | 2 | Se | 3.5 | Zr | 53 | ||
| Hg | 0.3 | ||||||
Denver, Colorado
revised August 2001
Dr. Stephen Wilson
Reference Material Project
Crustal Imaging and Characterization Team
Abbey, S., 1983, Studies in "Standard Samples" of Silicate Rocks and Minerals 1969-1982, Canadian Geological Survey Paper 83-15, p-114.
Flanagan, F.J., 1976, Descriptions and Analyses of Eight New USGS Rock Standards, U.S. Geological Survey Professional Paper 840, p 192.
Gladney E.S., and Roelandts, I., 1988, 1987 Compilation of Elemental Concentration Data for USGS BHVO-1, MAG-1, QLO-1, RGM-1, SCo-1, SDC-1, SGR-1, and STM-1, Geostandards Newsletter, 12: 253-362.
Govindaraju, K., 1994, 1994 Compilation of Working Values and Descriptions for 383 Geostandards, Geostandards Newsletter, 18:1-158.
| Symbol | Definition |
|---|---|
| Fe2O3T | Total iron expressed as Fe2O3 |
| Ctot | Total carbon concentration |
| Cinorg | Inorganic carbon concentration |
| Stot | Total sulfur concentration |
| Wt % | Percent of total element concentration |
| µg/g | Total element concentration expressed as micrograms of element per gram of solid sample |
| ± | One standard deviation |
Unless otherwise indicated total element concentrations are reported for material on an as-received basis, i.e., no drying.
USGS reference materials (RMs) may be obtained directly from Dr. Stephen A. Wilson. The price for each bottle of RM is $80.00 (U.S. dollars) except DGPM-1, which is $175.00 (U.S. dollars). For domestic orders, this cost includes all shipping and handling charges using normal mail delivery. For foreign orders, delivery charges will be added to the final bill. Urgent requests for RMs should be initiated by Fax or e-mail. If required, overnight delivery is available with these charges added to the final bill.
Dr. Stephen A. Wilson
U.S. Geological Survey
Box 25046, MS 964
Denver, CO 80225
Tel: 303-236-2454
FAX: 303-236-3200 or 303-236-1425
e-mail: (swilson)
Domestic customers: Payment options include purchase order, check, money order, or credit card (Visa, Mastercard).
International customers: Payment on foreign orders can only be made using the following:
Payments for domestic or international orders using a credit card receive a 10% discount on the per bottle price.
Beginning in 2006, users of USGS geochemical reference standards must complete a user agreement form prior to the order being purchased.
User agreement for domestic users: Word format, 56 KB and PDF format, 24 KB.
User agreement for foreign users: Word format, 56 KB and PDF format, 28 KB.
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URL: http://minerals.cr.usgs.gov/geo_chem_stand/shale.html
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Page Last Modified: 12-Mar-2009@20:54
